Dynamical field theory for glass-forming liquids, self-consistent resummations and time-reversal symmetry

نویسنده

  • A. Andreanov
چکیده

We analyze the symmetries and the self-consistent perturbative approaches of dynamical field theories for glass-forming liquids. In particular we focus on the time-reversal symmetry which is crucial to obtain fluctuation dissipation relations (FDR). Previous field theoretical treatment violated this symmetry, whereas others pointed out that constructing symmetry preserving perturbation theories is a crucial and open issue. In this work we solve this problem and then apply our results to the Mode Coupling Theory of the glass transition (MCT). We show that in the context of dynamical field theories for glassforming liquids time-reversal symmetry is expressed as a non-linear field transformation that leaves the action invariant. Because of this non-linearity standard perturbation theories generically do not preserve time-reversal symmetry and in particular fluctuation-dissipation relations. We show how one can cure this problem and set up symmetry preserving perturbation theories by introducing some auxiliary fields. As an outcome we obtain Schwinger-Dyson dynamical equations that preserve automatically FDR and that serve as a basis for carrying out symmetry preserving approximations. We apply our results to the Mode-Coupling Theory of the glass transition revisiting previous field theory derivations of MCT equations and showing that they generically violate FDR. We obtain symmetry preserving modecoupling equations and discuss their advantages and drawbacks. Furthermore we show, contrary to previous works, that the structure of the dynamic equations is such that the ideal glass transition is not cut-off at any finite order of perturbation theory, even in the presence of coupling between current and density. The opposite results found in previous field theoretical works, as the ones based on non-linear fluctuating hydrodynamics, were only due to an incorrect treatment of time-reversal symmetry.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Dynamic criticality in glass-forming liquids.

We propose that the dynamics of supercooled liquids and the formation of glasses can be understood from the existence of a zero-temperature dynamical critical point. To support our proposal, we derive a dynamic field theory for a generic kinetically constrained model, which we expect to describe the dynamics of a supercooled liquid. We study this field theory using the renormalization group (RG...

متن کامل

Glassy slowdown and replica-symmetry-breaking instantons.

Glass-forming liquids exhibit a dramatic dynamical slowdown as the temperature is lowered. This can be attributed to relaxation proceeding via large structural rearrangements whose characteristic size increases as the system cools. These cooperative rearrangements are well modeled by instantons in a replica effective field theory, with the size of the dominant instanton encoding the liquid's ca...

متن کامل

Time-reversal symmetry in dynamical systems: a survey

In this paper we survey the topic of time-reversal symmetry in dynamical systems. We begin with a brief discussion of the position of time-reversal symmetry in physics. After defining time-reversal symmetry as it applies to dynamical systems, we then introduce a major theme of our survey, namely the relation of time-reversible dynamical sytems to equivariant and Hamiltonian dynamical systems. W...

متن کامل

A universal description of ultraslow glass dynamics

The dynamics of glass is of importance in materials science but its nature has not yet been fully understood. Here we report that a verification of the temperature dependencies of the primary relaxation time or viscosity in the ultraslowing/ultraviscous domain of glass-forming systems can be carried out via the analysis of the inverse of the Dyre-Olsen temperature index. The subsequent analysis...

متن کامل

Microscopic theory of network glasses.

A theory of the glass transition of network liquids is developed using self-consistent phonon and liquid state approaches. The dynamical transition and entropy crisis characteristic of random first-order transitions are mapped as a function of the degree of bonding and density. Using a scaling relation for a soft-core model to crudely translate the densities into temperatures, theory predicts t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2005